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(defun c:compare2three (/ entered_num) (setq entered_num (getint \nEnter an integer: )) (if (< entered_num 3) (princ \nThe entered number is less than 3. ) (if (= entered_num 3) (princ \nThe entered number is equal to 3. ) (princ \nThe entered number is greater than 3. ) ) ) (princ) )

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net/zliboutput-compression-level ;zliboutput_compression_level = -1 ; You cannot specify additional output handlers if zliboutput_compression ; is activated here This setting does the same as output_handler but in ; a different order ; http://phpnet/zliboutput-handler ;zliboutput_handler = ; Implicit flush tells PHP to tell the output layer to flush itself ; automatically after every output block This is equivalent to calling the ; PHP function flush() after each and every call to print() or echo() and each ; and every HTML block Turning this option on has serious performance ; implications and is generally recommended for debugging purposes only ; http://phpnet/implicit-flush ; Note: This directive is hardcoded to On for the CLI SAPI implicit_flush = Off ; The unserialize callback function will be called (with the undefined class ; name as parameter), if the unserializer finds an undefined class ; which should be instantiated.

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equally distributed between the 2-, 3-, 5-, and 6-positions It is probable that preference for the 3- and 5-positions originates from the lower activation energy, leading to the 2-azapentadienyl dication intermediate The 2-, and 1-azapentadienyl dications serve as models for the transition states Their SHMO p energies are 4 6X908j j and 4 6X810j j, respectively Substitution into the 4-position of pyridine may be accomplished directly via the N-oxide, whose HOMO is shown in Figure 116d On the basis of the SHMO calculation, one would expect greatly enhanced reactivity for the N-oxide, although polarization of the HOMO indicates that electrophilic attack would occur predominantly on the oxygen if it is not protonated under the reaction conditions NUCLEOPHILIC SUBSTITUTIONS Nucleophilic substitution in aromatic systems occurs by two very di erent mechanisms: initial proton abstraction and initial addition to the p system The former will be discussed separately below.

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In the present section, we will restrict our consideration to reactions of substituted benzenes and to nitrogen heteroaromatic systems in which the reaction takes place rst with the p system The simplest example of reaction of a substituted benzene with a nucleophile (Lewis base) is shown in Scheme 112 This scheme is entirely analogous to Scheme 111, which described electrophilic attack, with the exception that hydrogen elimination (as hydride in step D) is not normally feasible The nucleophile may attach itself to the p system (step A) in four distinct modes relative to a reference substituent, G, namely ipso, ortho, meta, and para The reactivity of the aromatic ring and the mode of attachment of the nucleophile will be in uenced by the speci c nature of the substituent group, which may be X:, Z, or ``C'' type.

Detachment of the nucleophile (step B) is most probable from all intermediates unless the group G itself is such that it can detach as a stable nucleophile (step C) or there is such a group (L) situated at the site of attack In the event that a leaving group, L, is present at the site of attack, the most likely second step is loss of that group (step D), yielding an ortho, meta, or para substitution product, as the case may be..

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